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V. 095 I investigated the reactivity of concentrates of resins and asphaltenes obtained in deasphalting naphtha residues and in redox reactions in processing of acid tars [1-3]. , were investigated. Practically important new products characterized by elevated thermal and radiation stability and low cost were obtained from the products of chemical transformations. Synthesis of new products from petroleum asphaltites – epoxy-containing derivatives – is described and the results of a study of their properties are reported.

The presence of absorption bands in the 1050 cm -1 region indicates the presence of primary OH groups in the products, and those in the 1100 cm-1 region indicate the presence of secondary OH groups. Bands of hydroxyl groups with hydrogen bonds appear in the 3500-3300 cm -1 region. The bands in the 1385 cm-1 region correspond to plane deformation vibrations of associated OH groups [6]. The bands in the 1080-1115 cm -1 region indicate different C – O – C bond stretching vibrations. There are also bands characteristic of the chloromethyl group.

Alkylation was conducted in the presence of aluminum chloride (4% in olefins) at 60°C and feedstock:olefins mass ratio of 1:1 for 3 h. The products were fractionated to separate the >350°C fraction. After treatment with the olefins, the VI of the paraffins and naphthenes and aromatics increased. Hydrocarbon fractions I and II separated from the initial feedstock had average molecular weights of 309-345, and their “average” molecules contained 22-25 carbon atoms and 35-40 hydrogen atoms. The H:C atomic ratios are characteristic of paraffin and naphthene and aromatic concentrates, except for fraction IV.

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